基本情况
姓名：陈小明
性别：男
职位：教授，博士生导师。2009年当选中国科学院院士。
联系方式
电话：+86-020-84113986
通讯地址：广州市新港西路 5g影院
邮编：510275
个人网站：//5gmovies.net/cxm/
教育经历
1983年获 5g影院 理学学士学位；
1986年获 5g影院 理学硕士学位；
1992年获香港中文大学哲学博士学位。
工作经历
主要工作简历：
1986年至1989年在中山医科大学生物化学教研室工作，历任助教、讲师
1992年7月起在 5g影院 化学与化学工程学院工作
1993年12月晋升副教授，1995年1月晋升教授
2006年至2020年担任生物无机与合成化学教育部重点实验室主任
2022年担任化学与精细化工广东省实验室主任
主要学术兼职：
先后兼任生物无机与合成化学教育部重点实验室主任、中大化学院院长、中国晶体学会副理事长、中国科学院化学部常委及副主任、国家学位委员会化学学科评议组成员、国家基金委化学部专家咨询委员会成员、国际分子筛协会金属有机框架材料（MOF）委员会成员等职务等。
讲授课程
主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程；指导博士后、博士生、硕士生以及国内访问学者的科研工作。
科研方向
功能配位化学与晶体工程研究，特别是配位聚合物、金属有机框架材料等的设计与合成、结构与功能（吸附与分离、催化、光电磁、传感）研究，以及含能分子晶体研究。
获奖情况
2007年 国家自然科学奖二等奖（第一完成人）：配合物控制合成与晶体工程方法基础研究
2008年 汤森路透卓越研究奖 (Thomson Reuters Research Fronts Award)
2012年 发展中国家科学院TWAS化学奖
2012年 广东省科学技术奖一等奖(第一完成人): “微孔与磁性配位聚合物研究”
2014年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2015年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2016年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2017年 科睿唯安高被引用科学家 (Clarivate Highly Cited Researcher)
2017年 广东省科学技术奖突出贡献奖
2018年 国家级教学成果二等奖（第三获得者）
2018年 科睿唯安高被引用科学家（Clarivate Highly Cited Researcher）
2019年 科睿唯安高被引用科学家（Clarivate Highly Cited Researcher）
2019年 第34届花剌子模国际科学奖(34th Khwarizmi International Award）
2020年 日本配位化学学会国际奖(International Award of Japan Society of Coordination Chemistry (JSCC)
2020年 科睿唯安高被引用科学家（Clarivate Highly Cited Researcher）
2021年 科睿唯安高被引用科学家（Clarivate Highly Cited Researcher）
论著一览
编写教材：
《单晶结构分析原理与实践》（与蔡继文博士合作），科学出版社，2003年9月第一版，2007年8月第二版。
陈小明在国际刊物发表的部分论文目录：
Selected Publications of Xiao-Ming Chen:
1. Polynuclear CuII12-MIII6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion:
[Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601.
2. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N. Angew. Chem. Int. Ed. 1999, 38, 2237-2240.
3. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031.
4. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883.
5. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202.
6. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209.
7. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219.
8. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565.
9. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506.
10. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082.
11. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163.
12. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559.
13. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314.
14. (Review Article) Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170.
15. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498.
16. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. ()
17. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739.
18. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538.
19. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017;
20. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2009, 131, 5516–5521. () .
21. (Review Article) Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M., Chem. Soc. Rev. 2009, 38, 2385–2396.
22. A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2009, 48, 5287-5290. .
23. Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2010, 132, 6654–6656.
24. Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M., Adv. Mater. 2011, 22, 1268–1271.
25. A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2011, 2, 2214-2218. .
26. Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2012, 3, 642. DOI: 10.1038/ncomms1654.
27. (Review Article) Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M., Chem. Rev. 2012, 112, 1001–1033.
28. Strong and dynamic CO2 sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2012, 134, 17380-17383.
29. A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 351–356.
30. Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 1539-1546.
31. Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2013, 4, 2534. DOI: 10.1038 /ncomms3534.
32. A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.; Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2013, 52, 13429-13433.
33. (Invited Review) Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M., Chem. Soc. Rev. 2014, 43, 5789-5814. DOI: 10.1039/C4CS00129J.
34. Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M., Adv. Funct. Mater. 2014, 24, 5866–5872. DOI: 10.1002/adfm.201401125.
35. Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen, Chem. Sci. 2014, 5, 4755. DOI: 10.1039/C4SC01505C.
36. Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming; Angew. Chem. Int. Ed. 2015, 54, 914 –918. DOI: 10.1002/anie.201408491.
37. Monodentate hydroxide as a super strong yet reversible active site for CO2 capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting; Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen, Energy Environ. Sci. 2015, 8, 1011-1016. DOI: 10.1039/C4EE02717E.
38. Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.; Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6350. doi:10.1038/ncomms7350.
39. Tuning fluorocarbon adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2015, 6, 2516-2521. DOI: 10.1039/C4SC03985H.
40. Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6917. DOI: doi: 10.1038/ncomms7917.
41. (Invited Review) Metal cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen, Coord. Chem. Rev. 2015, 293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009.
42. Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna, Rajamani; Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2015, 137, 7217–7223.
43. Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8348. DOI: 10.1038/ncomms9348.
44. Efficient purification of ethene by ethane-trapping metal-organic framework
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8697. doi:10.1038/ncomms9697.
45. (Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 4674–4678. DOI: 10.1002/anie.201511006.
46. An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei; Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming, J. Am. Chem. Soc. 2016, 138, 8336–8339. DOI: 10.1021/jacs.6b03125.
47. Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming; Adv. Mater., 2016, 28, 5886–5890. DOI: 10.1002/adma.201600895.
48. (Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO2
Kai-Jie Chen, David G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko, Angew. Chem. Int. Ed. 2016, 55, 10268–10272. DOI: 10.1002/anie.201603934.
49. Putting ultrahigh concentration of amine groups into a metal–organic framework for CO2 capture at low pressures
Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong; Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci. 2016, 7, 6528-6533. DOI: 10.1039/C6SC00836D.
50. Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 6021–16025. DOI: 10.1002/anie.201608439.
51. Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 1778–1781. DOI: 10.1021/jacs.6b12353.
52. A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan; He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 139, 5285–5288. DOI: 10.1021/jacs.7b00165.
53. A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 6369–6375. DOI: 10.1021/jacs.7b01334.
54. Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Science, 2017, 356, 1193-1196. DOI: 10.1126/science.aam7232.
55. A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi; Zhang, Wei-Xiong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 8086–8089. DOI: 10.1021/jacs.7b02981.
56. Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2017, 8, 7560–7565. DOI: 10.1039/c7sc03067c. Link
57. Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO2 reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng; J. Am. Chem. Soc. 2018, 140, 38–41.
58. Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long; Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming, Zhang, Jie-Peng; Adv. Mater. 2018, 30, 1704350. adma.201704350.
59. Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu, Xia; Du, Zi-Yi; He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2018, 10.1002/anie.201802580.
